N,N'-Dibutyl-1,6-hexanediamine → N,N'-(1,6-hexylene)-bis[N-butyl-2-hydroxyundecylamine]

HRID 1391127Notes

Reaction equation

[CH2:1]1[O:12][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([NH:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][NH:24][CH2:25][CH2:26][CH2:27][CH3:28])[CH2:14][CH2:15][CH3:16]>>[CH2:18]([N:17]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:13][CH2:14][CH2:15][CH3:16])[CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][N:24]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:25][CH2:26][CH2:27][CH3:28]

Participants

Reactant 2

HCID 20972N,N'-Dibutyl-1,6-hexanediamine

HCID 5377372-Nonyloxirane

Product 1

HCID 21332430N,N'-(1,6-hexylene)-bis[N-butyl-2-hydroxyundecylamine]

Procedure

Condensation of 1-undecene oxide and N,N'-dibutylhexamethylenediamine affords N,N'-(1,6-hexylene)-bis[N-butyl-2-hydroxyundecylamine] (I: R = CH3 (CH2)8, R' = CH3 (CH2)3, X = (CH2)6, Z = H).

Sources & evidence

ORD record: ord-5e6cd6548b6444dc90724bd4091c3430
Source dataset: uspto-grants-1979_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04140860

Reaction notes

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