Stannous Chloride → 3-Allyloxycarbonyl-5-aminobenzamide

Participants

Reaction Steps

3-Allyloxycarbonyl-5-nitrobenzamide (1 g) was reduced with SnCl2 by a similar method to the reduction in example 12, giving 3-allyloxycarbonyl-5-aminobenzamide (0.5 g). Nmr (DMSO-d6): 4.78 (dt, 2H); 5.2-5.8 (broad, 2H); 5.26-5.45 (m, 2H); 5.91-6.13 (m, 1H); 7.22 (broad s, 1H); 7.27 (t, 1H); 7.33 (t, 1H); 7.59 (s, 1H).

Provenance & Evidence