Potassium Chloride → Benzene, ethenyl-, polymer with 1,3-butadiene

HRID 1392290Notes

Reaction equation

HRID 1392290 reaction equation
O.O.S([O-])[O-].C=O.[Na+].[Na+].C(N(CC([O-])=O)CC([O-])=O)CN(CC([O-])=O)CC([O-])=O.[Na+].[Na+].[Na+].[Na+].[K].[CH3:35][CH:36]([C:38]1[CH2:47][CH2:46][C@H:45]2[C:40](=CC[C@H]3[C@@](C(O)=O)(C)CCC[C@@]32C)[CH:39]=1)C.[Cl-].[K+].P([O-])([O-])([O-])=O.[K+].[K+].[K+].[OH-].[Na+].[OH-].[K+].[O-]O.[CH:73]12CC([C:78]1(C)C)C[CH2:75][CH:74]2C>O>[CH2:35]=[CH:36][C:38]1[CH:47]=[CH:46][CH:45]=[CH:40][CH:39]=1.[CH2:78]=[CH:73][CH:74]=[CH2:75]

Participants

11

Reactant 9

HCID 4873Potassium ChlorideHCID 6144Edetate SodiumHCID 10569Abietic AcidHCID 14797Potassium HydroxideHCID 14798Sodium HydroxideHCID 62657Potassium Phosphate, TribasicHCID 5462222PotassiumHCID 22041929CID 22041929HCID 71438240Pinanehydroperoxide

Product 1

HCID 62697Benzene, ethenyl-, polymer with 1,3-butadiene

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The activator solution was a mixture of ferrous sulfate heptahydrate (in an amount of about 0.009 phm) where phm is parts by weight per 100 parts by weight of monomer sodium formaldehyde sulfoxylate dihydrate (in an amount of about 0.07 phm), tetrasodium ethylenediaminetetraacetate (in an amount of about 0.035 phm) and water (in an amount of about 9.97 phm). The soap solution was a mixture of mixed C14-C18 and C16-C18 unsaturated fatty acids (in an amount of about 2.34 phm), a potassium salt of disproportionated rosin acid (in an amount of about 1.4 phm), potassium chloride (in an amount of about 0.23 phm), tripotassium phosphate (in an amount of about 0.05 phm), diluted sodium hydroxide (in an amount of about 0.16 phm) and 50 weight percent potassium hydroxide (in an amount of about 0.18 phm). The initiator was pinane hydroperoxide (in an amount of about 0.05 phm).

Sources & evidence

ORD record
ord-65583457d96e43669e8d29e3dc7f2a50
Source dataset
uspto-grants-2008_03
Patent number
US07342065B2

Reaction notes

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