Dimethylamine → HCID 178482606, compound

HRID 1392893Notes

Reaction equation

HRID 1392893 reaction equation
O.[I-:2].[I-].[I-].[I-].[CH:6]1[C:19]2[C:10](=[S+:11][C:12]3[C:17]([N:18]=2)=[CH:16][CH:15]=[CH:14][CH:13]=3)[CH:9]=[CH:8][CH:7]=1.[CH:20]1[C:33]2[C:24](=[S+:25][C:26]3[C:31]([N:32]=2)=[CH:30][CH:29]=[CH:28][CH:27]=3)[CH:23]=[CH:22][CH:21]=1.[CH:34]1[C:47]2[C:38](=[S+:39][C:40]3[C:45]([N:46]=2)=[CH:44][CH:43]=[CH:42][CH:41]=3)[CH:37]=[CH:36][CH:35]=1.C1[C:61]2C(=[S+]C3[C:59]([N:60]=2)=CC=CC=3)C=CC=1.[CH3:62][NH:63][CH3:64]>CO>[I-:2].[I-:2].[I-:2].[CH3:31][N:32]([CH3:33])[C:8]1[CH:7]=[CH:6][C:19]2[C:10]([CH:9]=1)=[S+:11][C:12]1[C:17](=[CH:16][CH:15]=[CH:14][CH:13]=1)[N:18]=2.[CH3:59][N:60]([C:36]1[CH:35]=[CH:34][C:47]2[C:38]([CH:37]=1)=[S+:39][C:40]1[C:45](=[CH:44][CH:43]=[CH:42][CH:41]=1)[N:46]=2)[CH3:61].[CH3:62][N:63]([C:22]1[CH:21]=[CH:20][C:33]2[C:24]([CH:23]=1)=[S+:25][C:26]1[C:31](=[CH:30][CH:29]=[CH:28][CH:27]=1)[N:32]=2)[CH3:64]

Participants

4

Reactant 2

HCID 674DimethylamineHCID 86590641HCID 86590641, compound

Product 1

HCID 178482606HCID 178482606, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

A solution of phenothiazine-5-ium tetraiodide hydrate (0.417 g, 0.57 mmol) in methanol (10 ml) was stirred at room temperature and treated dropwise with a solution of dimethylamine (1.14 mmole) in methanol (2 ml). The mixture was stirred at room temperature for 3 hrs until the starting materials was consumed, as monitored by TLC (silica, CH3OH/TEA). The precipitate was filtered and washed with small amount of methanol, afforded a black solid, 0.30 g (84%).

Workup

  1. customwas consumed
  2. filtrationThe precipitate was filtered
  3. washwashed with small amount of methanol
  4. customafforded a black solid, 0.30 g (84%)

Sources & evidence

ORD record
ord-828591278c004d558f4464da7645b62a
Source dataset
uspto-grants-2008_03
Patent number
US07344823B2

Reaction notes

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