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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1395064Generated: October 26, 2026

Ammonia → Dimethyldipropylenetriamine

https://huagongshe.com/reaction/1395064

Reaction equation

Participants

RoleNameHCIDCharge
ReactantAmmoniaHCID 222—
Reactant3-((3-(Dimethylamino)propyl)amino)propanenitrileHCID 112322—
CatalystNickelHCID 935—
SolventIsopropanolHCID 3776—
ProductDimethyldipropylenetriamineHCID 82728—

Reaction Steps

216 g of N,N-dimethyl-N'-(β-cyanoethyl)-1,3-diaminopropane are hydrogenated in 216 ml of isopropanol in the presence of 140 g of gaseous ammonia and 13 g of Raney nickel in an autoclave at 120° C. and under an initial pressure of 80 atmospheres until the pressure remains constant, which is already the case after 30 minutes. The catalyst is filtered off with suction, the filtrate is concentrated in a rotary evaporator and the residue is distilled through a packed column. Yield: 205.7 g (92.8%); boiling point 121° C./11 mm Hg.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04201854
Source datasetuspto-grants-1980_05
ORD IDord-cb7ebbf5dae847e59f7395c398982eda
Source noteuspto-grants-1980_05