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HRID1395237

反应详情

EQUATION

反应方程式

HRID 1395237 的结构方程式

REACTANTS

反应物

2
结构：[Cl-].[K+]
HCID4873

Potassium chloride

ClK

结构：CC(C)CCC[C@@H](C)[C@H]1CC(=O)C2=C3CC[C@H]4C[C@@H]([n+]5ccccc5)CC[C@]4(C)[C@H]3CC[C@@]21C.CC(C)CCC[C@@H](C)[C@H]1CC(=O)C2=C3CC[C@H]4C[C@@H]([n+]5ccccc5)CC[C@]4(C)[C@H]3CC[C@@]21C.O=S(=O)([O-])[O-]
HCID86736984

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)CCC[C@@H](C)[C@H]1CC(=O)C2=C3CC[C@H]4C[C@@H]([K])CC[C@]4(C)[C@H]3CC[C@@]21C.O=S(=O)(O)O
HCID178443928

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

5α-Cholest-8(14)-en-15-on-3β-yl pyridinium sulfate (1.0 g; 1.79 mmol) was dissolved in distilled water (50 ml) at room temperature and an aqueous saturated solution of potassium chloride was slowly added to the stirred mixture. After 15 min the resulting suspension was filtered, washed with water, and dried in a vacuum desiccator for several hours. The resulting white residue (0.85 g; 89%), was shown by i.r., n.m.r., and m.s. analyses to be 5α-cholest-8(14)-en-15-on-3β-yl potassium sulfate (monohydrate) having the structure: ##STR56##

WORKUP

后处理

  1. filtrationAfter 15 min the resulting suspension was filtered
  2. washwashed with water
  3. customdried in a vacuum desiccator for several hours