HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Bromopropane → Isopropyl(2-nitrophenyl)sulfane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Bromopropane | HCID 6358 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | o-Nitrobenzenethiol | HCID 21002 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | Isopropyl(2-nitrophenyl)sulfane | HCID 12505026 | — |
Reaction Steps
2-Nitrothiophenol, 2-bromopropane, potassium carbonate and acetone were refluxed for several hours. The solvent then was removed by rotary evaporation. The crude product was partitioned between methylene chloride and a 10% sodium carbonate solution. The organic phase was distilled to yield 2-isopropylmercaptonitrobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04203901 |
| Source dataset | uspto-grants-1980_05 |
| ORD ID | ord-201da4c79eaa4044b4726adb7c352354 |
| Source note | uspto-grants-1980_05 |