Hydrazine → HCID 20339225, compound

HRID 1395387Notes

Reaction equation

HRID 1395387 reaction equation
C1(=O)[N:5]([CH2:6][CH2:7][CH2:8][S:9][CH2:10][C:11]2[O:12][C:13]([CH2:16][N:17]([CH3:19])[CH3:18])=[CH:14][CH:15]=2)C(=O)C2=CC=CC=C12.NN.[C:28]([N:30]=[C:31]([S:34][CH3:35])SC)#[N:29]>>[C:28]([NH:30][C:31](=[N:5][CH2:6][CH2:7][CH2:8][S:9][CH2:10][C:11]1[O:12][C:13]([CH2:16][N:17]([CH3:18])[CH3:19])=[CH:14][CH:15]=1)[S:34][CH3:35])#[N:29]

Participants

4

Reactant 3

HCID 9321HydrazineHCID 66289Dimethyl N-cyanodithioiminocarbonateHCID 20504322HCID 20504322, compound

Product 1

HCID 20339225HCID 20339225, compound

Procedure

When 1-phthalimido-3-[(5-dimethylaminomethyl-2-furyl)methylthio]propane is treated with hydrazine and the resultant substituted propylamine is reacted with dimethyl cyanodithioimidocarbonate there is produced N-cyano-N'-{3-[(5-dimethylaminomethyl-2-furyl)methylthio]propyl}-S-methylisothiourea, and when this is reacted with propargylamine according to the general procedure of Example 3 the title compound is produced.

Sources & evidence

ORD record
ord-5547914a00714a74a182b24e061f11b7
Source dataset
uspto-grants-1980_05
Patent number
US04203909

Reaction notes

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