HCID 86736991, compound → HCID 86736991, compound

HRID 1395463Notes

Reaction equation

HRID 1395463 reaction equation
[O:1]([CH2:8][CH2:9][NH:10][C:11]([S-:13])=[S:12])[CH2:2][CH2:3][NH:4][C:5]([S-:7])=[S:6].[NH4+:14].[NH4+]>O>[O:1]([CH2:8][CH2:9][NH:10][C:11]([S-:13])=[S:12])[CH2:2][CH2:3][NH:4][C:5]([S-:7])=[S:6].[NH4+:14].[NH4+:4].[O:1]([CH2:8][CH2:9][NH:10][C:11]([S-:13])=[S:12])[CH2:2][CH2:3][NH:4][C:5]([S-:7])=[S:6]

Participants

4

Reactant 1

HCID 86736991HCID 86736991, compound

Product 2

HCID 86736991HCID 86736991, compoundHCID 86736993HCID 86736993, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

To a solution of 10.15 g (0.0351 mole) of Compound 1 in 200 ml H2O was added, with stirring and over a period of 30 minutes, a solution of 9.67 g (0.336 mole) ZnSO4.7H2O and 0.30 g (0.018 mole) MnSO4.7H2O dissolved in 25 ml H2O. The resulting precipitate was filtered, washed once with water and once with methanol, and dried under vacuum in a dessicator for 7 hours, to yield 10.8 g (96.5 percent of theory, calculated from Compound 1) of the titled compound as a fine purple powder.

Workup

  1. filtrationThe resulting precipitate was filtered
  2. washwashed once with water and once with methanol
  3. customdried under vacuum in a dessicator for 7 hours

Sources & evidence

ORD record
ord-a10c024c6f6c45838a265d59c63b0c4c
Source dataset
uspto-grants-1980_05
Patent number
US04203999

Reaction notes

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