참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Ethanol | HCID 702 | — |
| 반응물 | Sodium Hydroxide | HCID 14798 | — |
| 반응물 | Chlorosulfonic acid | HCID 24638 | — |
| 반응물 | Tricyclohexylbenzene | HCID 3015433 | — |
| 용매 | Dichloromethane | HCID 6344 | — |
| 생성물 | Sodium 1,3,5-tricyclohexylbenzenesulfonate | HCID 86655172 | — |
반응 단계
Tricyclohexylbenzene amounting to 30 g was dissolved in 50 ml of methylene chloride, and agitated while cooling at 3° C. Then, 15.2 g of chlorosulfonic acid was slowly dropped thereinto. After the completion of the dropping, the mixture was agitated at room temperature for 5 hours, and 10 g of ice was poured thereinto. Further, 40 g of a 50% aqueous solution of sodium hydroxide was poured into the mixture, and 20 g of ethanol was added thereto. The mixture was agitated at 50° C. for 1 hour, and any undissolved matter was removed by filtration. Vacuum distillation was carried out at 40° C., and separated crystals were collected by filtration. The crystals were washed with hexane. Thus, 30 g of sodium 1,3,5-tricyclohexylbenzenesulfonate was obtained.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 특허 번호 | US08900791B2 |
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| 출처 데이터셋 | uspto-grants-2014_12 |
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| ORD ID | ord-a8e0a94e45e64799a2c217734f46777e |
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| 출처 메모 | uspto-grants-2014_12 |
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