Lithium bis((trifluoromethyl)sulfonyl)azanide → HCID 178439596, compound

HRID 1399390Notes

Reaction equation

HRID 1399390 reaction equation
[I-].[CH3:2][O:3][CH2:4][CH2:5][O:6][CH2:7][CH2:8][O:9][CH2:10][CH2:11][N:12]1[CH:16]=[C:15]([CH2:17][CH2:18][CH3:19])[N+:14]([CH3:20])=[N:13]1.[F:21][C:22]([F:35])([F:34])[S:23]([N-:26][S:27]([C:30]([F:33])([F:32])[F:31])(=[O:29])=[O:28])(=[O:25])=[O:24].[Li+]>C(#N)C>[F:33][C:30]([F:31])([F:32])[S:27]([N-:26][S:23]([C:22]([F:21])([F:34])[F:35])(=[O:24])=[O:25])(=[O:28])=[O:29].[CH3:2][O:3][CH2:4][CH2:5][O:6][CH2:7][CH2:8][O:9][CH2:10][CH2:11][N:12]1[CH:16]=[C:15]([CH2:17][CH2:18][CH3:19])[N+:14]([CH3:20])=[N:13]1

Participants

4

Reactant 2

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanideHCID 178439595HCID 178439595, compound

Product 1

HCID 178439596HCID 178439596, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

1-(2-(2-(2-methoxyethoxy)ethoxy)ethyl)-3-methyl-4-propyl-1H-1,2,3-triazol-3-ium iodide and lithium bis((trifluoromethyl)sulfonyl)amide were mixed in acetonitrile and stirred overnight. The acetonitrile was removed under vacuum and water and DCM added. The organic layer was washed three times with water and brine and dried in vacuum at 110° C. for 48 hours, yielding 1-(2-(2-(2-methoxyethoxy)ethoxy)ethyl)-3-methyl-4-propyl-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide.

Workup

  1. customThe acetonitrile was removed under vacuum and water and DCM
  2. additionadded
  3. washThe organic layer was washed three times with water and brine
  4. customdried in vacuum at 110° C. for 48 hours

Sources & evidence

ORD record
ord-7e78006f063a43be8778e3f9f15bd9d1
Source dataset
uspto-grants-2014_12
Patent number
US08906135B1

Reaction notes

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