Lithium bis((trifluoromethyl)sulfonyl)azanide → HCID 178439610, compound

HRID 1399404Notes

Reaction equation

HRID 1399404 reaction equation
[I-].[CH3:2][N+:3]1[C:7]([CH2:8][CH2:9][CH3:10])=[CH:6][N:5]([CH2:11][Si:12]([CH3:15])([CH3:14])[CH3:13])[N:4]=1.[F:16][C:17]([F:30])([F:29])[S:18]([N-:21][S:22]([C:25]([F:28])([F:27])[F:26])(=[O:24])=[O:23])(=[O:20])=[O:19].[Li+]>C(#N)C>[F:28][C:25]([F:26])([F:27])[S:22]([N-:21][S:18]([C:17]([F:16])([F:29])[F:30])(=[O:19])=[O:20])(=[O:23])=[O:24].[CH3:2][N+:3]1[C:7]([CH2:8][CH2:9][CH3:10])=[CH:6][N:5]([CH2:11][Si:12]([CH3:15])([CH3:13])[CH3:14])[N:4]=1

Participants

4

Reactant 2

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanideHCID 178439609HCID 178439609, compound

Product 1

HCID 178439610HCID 178439610, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide and lithium bis((trifluoromethyl)sulfonyl)amide were mixed in acetonitrile and stirred overnight. The acetonitrile was removed under vacuum and water and DCM added. The organic layer was washed three times with water and brine and dried in vacuum at 110° C. for 48 hours, yielding 3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide.

Workup

  1. customThe acetonitrile was removed under vacuum and water and DCM
  2. additionadded
  3. washThe organic layer was washed three times with water and brine
  4. customdried in vacuum at 110° C. for 48 hours

Sources & evidence

ORD record
ord-5c9f615073de456b8655b57c49be1f4f
Source dataset
uspto-grants-2014_12
Patent number
US08906135B1

Reaction notes

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