Lithium bis((trifluoromethyl)sulfonyl)azanide → HCID 178439610, compound

HRID 1401385Notes

Reaction equation

HRID 1401385 reaction equation
[I-].[CH3:2][N+:3]1[C:7]([CH2:8][CH2:9][CH3:10])=[CH:6][N:5]([CH2:11][Si:12]([CH3:15])([CH3:14])[CH3:13])[N:4]=1.[F:16][C:17]([F:30])([F:29])[S:18]([N-:21][S:22]([C:25]([F:28])([F:27])[F:26])(=[O:24])=[O:23])(=[O:20])=[O:19].[Li+]>C(#N)C>[F:28][C:25]([F:26])([F:27])[S:22]([N-:21][S:18]([C:17]([F:16])([F:29])[F:30])(=[O:19])=[O:20])(=[O:23])=[O:24].[CH3:2][N+:3]1[C:7]([CH2:8][CH2:9][CH3:10])=[CH:6][N:5]([CH2:11][Si:12]([CH3:15])([CH3:13])[CH3:14])[N:4]=1

Participants

4

Reactant 2

HCID 3816071Lithium bis((trifluoromethyl)sulfonyl)azanideHCID 178439609HCID 178439609, compound

Product 1

HCID 178439610HCID 178439610, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium iodide and lithium bis((trifluoromethyl)sulfonyl)amide were mixed in acetonitrile and stirred overnight. The acetonitrile was removed under vacuum and water and DCM added. The organic layer was washed three times with water and brine and dried in vacuum at 110° C. for 48 hours, yielding 3-methyl-4-propyl-1-((trimethylsilyl)methyl)-1H-1,2,3-triazol-3-ium bis((trifluoromethyl)sulfonyl)amide.

Workup

  1. customThe acetonitrile was removed under vacuum and water and DCM
  2. additionadded
  3. washThe organic layer was washed three times with water and brine
  4. customdried in vacuum at 110° C. for 48 hours

Sources & evidence

ORD record
ord-ea440389a4c845aea73a221e087de21f
Source dataset
uspto-grants-2014_12
Patent number
US08907105B1

Reaction notes

Loading…