Veratraldehyde → HCID 89500867, compound

HRID 1401722Notes

Reaction equation

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]2[O:8][CH2:9][C:10]([CH2:12][O:13][C:4]=2[CH:3]=1)=[O:11].[CH3:14][O:15][C:16]1[CH:17]=[C:18]([CH:21]=[CH:22][C:23]=1[O:24][CH3:25])[CH:19]=O>>[CH3:14][O:15][C:16]1[CH:17]=[C:18](/[CH:19]=[C:9]2/[C:10](=[O:11])/[C:12](=[CH:1]/[C:2]3[CH:7]=[CH:6][C:5]([O:8][CH3:9])=[C:4]([O:13][CH3:12])[CH:3]=3)/[O:13][C:4]3[CH:3]=[C:2]([CH3:1])[CH:7]=[CH:6][C:5]=3[O:8]/2)[CH:21]=[CH:22][C:23]=1[O:24][CH3:25]

Participants

Reactant 2

HCID 8419Veratraldehyde

HCID 120101Methyl benzodioxepinone

Product 1

HCID 89500867HCID 89500867, compound

Procedure

Calone is reacted with 3,4-dimethoxybenzaldehyde analogously to the reaction conditions of Example 1, giving 2,4-bis[1-(3,4-dimethoxyphenyl)-meth-(Z)-ylidene]-7-methylbenzo[b]-1,4-dioxepin-3-one.

Sources & evidence

ORD record: ord-44cabe350db1496ba1b9e54e0b477865
Source dataset: uspto-grants-2014_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08907110B2

Reaction notes

Loading…