4-Phenoxybenzaldehyde → HCID 89500859, compound

HRID 1401726Notes

Reaction equation

[CH3:1][C:2]1[CH:7]=[CH:6][C:5]2[O:8][CH2:9][C:10]([CH2:12][O:13][C:4]=2[CH:3]=1)=[O:11].[O:14]([C:21]1[CH:28]=[CH:27][C:24]([CH:25]=O)=[CH:23][CH:22]=1)[C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]2[O:8]/[C:9](=[CH:25]\[C:24]3[CH:27]=[CH:28][C:21]([O:14][C:15]4[CH:16]=[CH:17][CH:18]=[CH:19][CH:20]=4)=[CH:22][CH:23]=3)/[C:10](=[O:11])/[C:12](=[CH:25]/[C:24]3[CH:27]=[CH:28][C:21]([O:14][C:15]4[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=4)=[CH:22][CH:23]=3)/[O:13][C:4]=2[CH:3]=1

Participants

Reactant 2

HCID 661394-Phenoxybenzaldehyde

HCID 120101Methyl benzodioxepinone

Product 1

HCID 89500859HCID 89500859, compound

Procedure

Calone is reacted with 4-phenoxybenzaldehyde analogously to the reaction conditions of Example 1, giving 7-methyl-2,4-bis[1-(4-phenoxyphenyl)meth-(Z)-ylidene]benzo[b]-1,4-dioxepin-3-one.

Sources & evidence

ORD record: ord-8900363db96b4357ac9bac9380a446e8
Source dataset: uspto-grants-2014_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08907110B2

Reaction notes

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