4-Fluorobenzaldehyde → HCID 89500509, compound

HRID 1401727Notes

Reaction equation

HRID 1401727 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]2[O:8][CH2:9][C:10]([CH2:12][O:13][C:4]=2[CH:3]=1)=[O:11].[F:14][C:15]1[CH:22]=[CH:21][C:18]([CH:19]=O)=[CH:17][CH:16]=1>>[F:14][C:15]1[CH:22]=[CH:21][C:18](/[CH:19]=[C:9]2/[C:10](=[O:11])/[C:12](=[CH:19]/[C:18]3[CH:21]=[CH:22][C:15]([F:14])=[CH:16][CH:17]=3)/[O:13][C:4]3[CH:3]=[C:2]([CH3:1])[CH:7]=[CH:6][C:5]=3[O:8]/2)=[CH:17][CH:16]=1

Participants

3

Reactant 2

HCID 680234-FluorobenzaldehydeHCID 120101Methyl benzodioxepinone

Product 1

HCID 89500509HCID 89500509, compound

Procedure

Calone is reacted with 4-fluorobenzaldehyde analogously to the reaction conditions of Example 1, giving 2,4-bis[1-(4-fluorophenyl)meth-(Z)-ylidene]-7-methylbenzo[b]-1,4-dioxepin-3-one.

Sources & evidence

ORD record
ord-158b84a629d140478504ebbd21fcab3b
Source dataset
uspto-grants-2014_12
Patent number
US08907110B2

Reaction notes

Loading…