Methyl benzodioxepinone → HCID 89505384, compound

HRID 1401732Notes

Reaction equation

HRID 1401732 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]2[O:8][CH2:9][C:10]([CH2:12][O:13][C:4]=2[CH:3]=1)=[O:11].[CH3:14][N:15]([CH3:28])[C:16]1[C:25]2[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=2)[C:19]([CH:26]=O)=[CH:18][CH:17]=1>>[CH3:14][N:15]([CH3:28])[C:16]1[C:25]2[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=2)[C:19](/[CH:26]=[C:9]2/[C:10](=[O:11])/[C:12](=[CH:26]/[C:19]3[C:20]4[C:25](=[CH:24][CH:23]=[CH:22][CH:21]=4)[C:16]([N:15]([CH3:14])[CH3:28])=[CH:17][CH:18]=3)/[O:13][C:4]3[CH:3]=[C:2]([CH3:1])[CH:7]=[CH:6][C:5]=3[O:8]/2)=[CH:18][CH:17]=1

Participants

3

Reactant 2

HCID 120101Methyl benzodioxepinoneHCID 6080524-Dimethylamino-1-naphthaldehyde

Product 1

HCID 89505384HCID 89505384, compound

Procedure

Calone is reacted with 4-dimethylaminonaphthalene-1-carbaldehyde analogously to the reaction conditions of Example 1, giving 2,4-bis[1-(4-dimethylaminonaphthalen-1-yl)meth-(Z)-ylidene]-7-methylbenzo[b]-1,4-dioxepin-3-one.

Sources & evidence

ORD record
ord-6d9b6fd358e44f889ddc42ac05aee492
Source dataset
uspto-grants-2014_12
Patent number
US08907110B2

Reaction notes

Loading…