HuagongsheHuagongshe Chemistry Print Report · For research reference only
Stannous chloride dihydrate → 4-Iodobenzene-1,2-diamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Reactant | 4-Iodo-2-nitroaniline | HCID 11369072 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | 4-Iodobenzene-1,2-diamine | HCID 11207049 | 92% |
Reaction Steps
Commercial 4-iodo-2-nitroaniline was reduced with 5 eq tin dichloride dihydrate in ethanol solution (75° C., 2 h) to give 92% 4-iodo-1,2-phenylenediamine as light red solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08912186B2 |
| Source dataset | uspto-grants-2014_12 |
| ORD ID | ord-1d0f7778bc77491387784c13b80185c3 |
| Source note | uspto-grants-2014_12 |