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Sodium acetate trihydrate (6 g) was added to a solution of commercial ethyl chloroacetate (6.2 g) and commercial 4-chloroaniline (6.4 g) in ethanol (5 ml). The mixture was heated to reflux for 5 h. After cooling in an ice bath the product precipitates. The solid was collected by suction filtration and washed with water. The still wet product was recrystallised from ethanol to give ethyl N-(4-chlorophenyl)glycinate (5.99 g) as greyish crystals.

1. temperatureThe mixture was heated
2. temperatureto reflux for 5 h
3. temperatureAfter cooling in an ice bath the product
4. customprecipitates
5. filtrationThe solid was collected by suction filtration
6. washwashed with water
7. customThe still wet product was recrystallised from ethanol