3-(3-Chlorophenyl)-1-phenylpropan-1-one → HCID 44220494, compound

HRID 1402885Notes

Reaction equation

HRID 1402885 reaction equation
ClC1C=C(CCC(C2C=CC=CC=2)=O)C=CC=1.[Cl:18][C:19]1[CH:20]=[C:21]([CH2:25][CH2:26]/[C:27](/[C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)=[CH:28]/[C:29]([O:31][CH2:32][CH3:33])=[O:30])[CH:22]=[CH:23][CH:24]=1>>[Cl:18][C:19]1[CH:20]=[C:21]([CH2:25][CH2:26]/[C:27](/[C:34]2[CH:39]=[CH:38][CH:37]=[CH:36][CH:35]=2)=[CH:28]\[C:29]([O:31][CH2:32][CH3:33])=[O:30])[CH:22]=[CH:23][CH:24]=1

Participants

3

Reactant 2

HCID 6820903-(3-Chlorophenyl)-1-phenylpropan-1-oneHCID 44222814HCID 44222814, compound

Product 1

HCID 44220494HCID 44220494, compound

Procedure

By a procedure similar to that of example 1.85.3, starting from 3-(3-chlorophenyl)-1-phenylpropan-1-one, (Z)-ethyl 5-(3-chloro-phenyl)-3-phenylpent-2-enoate and (E)-ethyl 5-(3-chlorophenyl)-3-phenylpent-2-enoate were obtained as colourless oils.

Sources & evidence

ORD record
ord-e0b0439a933a4e02919d0830cd534aa6
Source dataset
uspto-grants-2014_12
Patent number
US08912186B2

Reaction notes

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