HCID 44220898, compound → HCID 44220897, compound

HRID 1402891Notes

Reaction equation

HRID 1402891 reaction equation
C(C1C=CC(CCC(C2C=CC=CC=2)=O)=CC=1)C.[CH2:19]([C:21]1[CH:26]=[CH:25][C:24]([CH2:27][CH2:28]/[C:29](/[C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)=[CH:30]/[C:31]([O:33][CH2:34][CH3:35])=[O:32])=[CH:23][CH:22]=1)[CH3:20]>>[CH2:19]([C:21]1[CH:26]=[CH:25][C:24]([CH2:27][CH2:28]/[C:29](/[C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)=[CH:30]\[C:31]([O:33][CH2:34][CH3:35])=[O:32])=[CH:23][CH:22]=1)[CH3:20]

Participants

3

Reactant 2

HCID 44220898HCID 44220898, compoundHCID 61970188HCID 61970188, compound

Product 1

HCID 44220897HCID 44220897, compound

Procedure

By a procedure similar to that of example 1.85.3, starting from 3-(4-ethylphenyl)-1-phenylpropan-1-one, (Z)-ethyl 5-(4-ethylphenyl)-3-phenylpent-2-enoate and (E)-ethyl 5-(4-ethylphenyl)-3-phenylpent-2-enoate were obtained as colourless oils.

Sources & evidence

ORD record
ord-d498fbea36c1483f814ede645bda025f
Source dataset
uspto-grants-2014_12
Patent number
US08912186B2

Reaction notes

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