HCID 13656084, compound → HCID 44220694, compound

HRID 1402897Notes

Reaction equation

HRID 1402897 reaction equation
ClC1C=C(CCC(C2C=CC=CC=2)=O)C=CC=1Cl.[Cl:19][C:20]1[CH:21]=[C:22]([CH2:27][CH2:28]/[C:29](/[C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)=[CH:30]/[C:31]([O:33][CH2:34][CH3:35])=[O:32])[CH:23]=[CH:24][C:25]=1[Cl:26]>>[Cl:19][C:20]1[CH:21]=[C:22]([CH2:27][CH2:28]/[C:29](/[C:36]2[CH:37]=[CH:38][CH:39]=[CH:40][CH:41]=2)=[CH:30]\[C:31]([O:33][CH2:34][CH3:35])=[O:32])[CH:23]=[CH:24][C:25]=1[Cl:26]

Participants

3

Reactant 2

HCID 13656084HCID 13656084, compoundHCID 44220695HCID 44220695, compound

Product 1

HCID 44220694HCID 44220694, compound

Procedure

By a procedure similar to that of example 1.85.3, starting from 3-(3,4-dichlorophenyl)-1-phenylpropan-1-one, (Z)-ethyl 5-(3,4-dichlorophenyl)-3-phenylpent-2-enoate and (E)-ethyl 5-(3,4-dichlorophenyl)-3-phenylpent-2-enoate were obtained as colourless oils.

Sources & evidence

ORD record
ord-7095f8751835474faba0db3c6f6b7889
Source dataset
uspto-grants-2014_12
Patent number
US08912186B2

Reaction notes

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