HCID 43175811, compound → HCID 44220696, compound

HRID 1402901Notes

Reaction equation

HRID 1402901 reaction equation
ClC1C=C(Cl)C=CC=1CCC(C1C=CC=CC=1)=O.[Cl:19][C:20]1[CH:25]=[C:24]([Cl:26])[CH:23]=[CH:22][C:21]=1[CH2:27][CH2:28]/[C:29](/[C:36]1[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=1)=[CH:30]/[C:31]([O:33][CH2:34][CH3:35])=[O:32]>>[Cl:19][C:20]1[CH:25]=[C:24]([Cl:26])[CH:23]=[CH:22][C:21]=1[CH2:27][CH2:28]/[C:29](/[C:36]1[CH:37]=[CH:38][CH:39]=[CH:40][CH:41]=1)=[CH:30]\[C:31]([O:33][CH2:34][CH3:35])=[O:32]

Participants

3

Reactant 2

HCID 43175811HCID 43175811, compoundHCID 44220697HCID 44220697, compound

Product 1

HCID 44220696HCID 44220696, compound

Procedure

By a procedure similar to that of example 1.85.3, starting from 3-(2,4-dichlorophenyl)-1-phenylpropan-1-one, (Z)-ethyl 5-(2,4-dichlorophenyl)-3-phenylpent-2-enoate and (E)-ethyl 5-(2,4-dichlorophenyl)-3-phenylpent-2-enoate were obtained as colourless oils.

Sources & evidence

ORD record
ord-85635b0b026d42a1995d7c5e07ec9afe
Source dataset
uspto-grants-2014_12
Patent number
US08912186B2

Reaction notes

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