2-(4-Chlorophenoxy)-1-phenylethanone → HCID 44220087, compound
Reaction equation
ClC1C=CC(OCC(C2C=CC=CC=2)=O)=CC=1.[Cl:18][C:19]1[CH:39]=[CH:38][C:22]([O:23][CH2:24]/[C:25](/[C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)=[CH:26]\[C:27]([O:29][CH2:30][CH3:31])=[O:28])=[CH:21][CH:20]=1>>[Cl:18][C:19]1[CH:20]=[CH:21][C:22]([O:23][CH2:24]/[C:25](/[C:32]2[CH:37]=[CH:36][CH:35]=[CH:34][CH:33]=2)=[CH:26]/[C:27]([O:29][CH2:30][CH3:31])=[O:28])=[CH:38][CH:39]=1Participants
3
Procedure
By a procedure similar to that of example 1.85.3, starting from 2-(4-chlorophenoxy)-1-phenylethanone, (Z)-ethyl 4-(4-chlorophenoxy)-3-phenylbut-2-enoate and (E)-ethyl 4-(4-chlorophenoxy)-3-phenylbut-2-enoate were obtained as colourless oils.
Sources & evidence
- ORD record
- ord-812ec76780e744dbb7834bdf9961a97a
- Source dataset
- uspto-grants-2014_12
- Patent number
- US08912186B2
Reaction notes
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