HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → (E)-2-(5-fluoro-2,4-dinitrophenyl)-N,N-dimethylethenamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Dimethylacetamide | HCID 31374 | — |
| Reactant | 1-Fluoro-5-methyl-2,4-dinitrobenzene | HCID 520705 | — |
| Solvent | Water | HCID 962 | — |
| Product | (E)-2-(5-fluoro-2,4-dinitrophenyl)-N,N-dimethylethenamine | HCID 15022335 | 63% |
Reaction Conditions
| Temperature | 100 °C |
|---|
Reaction Steps
A mixture of 1-fluoro-5-methyl-2,4-dinitro-benzene (10 g, 50 mmol), DMA (12 g, 100 mmol) and DMF (50 mL) was heated at 100° C. for 4 h. The solution was cooled and poured into water. The precipitated red solid was collected, washed with water, and dried to give (E)-2-(5-fluoro-2,4-dinitrophenyl)-N,N-dimethylethenamine (8.0 g, 63%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08912199B2 |
| Source dataset | uspto-grants-2014_12 |
| ORD ID | ord-1b699ce7c3d046ee8c13efeb88375867 |
| Source note | uspto-grants-2014_12 |