N-Ethylaniline → HCID 123622400, compound
Reaction equation
C(N[C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)C.[CH:10]([N:13]([SiH3:17])C(C)C)(C)[CH3:11]>>[C:4]1([CH2:11][CH2:10][NH:13][SiH3:17])[CH:5]=[CH:6][CH:7]=[CH:8][CH:9]=1Participants
3
Procedure
In a 500 ml Schlenk flask, 60.5 g (0.5 mol) N-ethylaniline and 131 g (1.0 mol) di-isopropylaminosilane were stirred at ambient temperature under a nitrogen atmosphere for 24 hours. The relatively lower boiling point by-product di-isopropylamine was removed with vacuum at a pressure of 20 mmHg and room temperature (25° C.). The reaction mixture was stirred for another 24 hours. The end-product phenylethylaminosilane was obtained by vacuum distillation. The end-product was characterized by mass spectroscopy (MS) which is provided in FIG. 2 and shows, among other things, peaks at 151, 150, 136, 120, 106, 93, and 77. The molecular weight of the phenylethylaminosilane was 151.28.
Workup
- customThe relatively lower boiling point by-product di-isopropylamine was removed with vacuum at a pressure of 20 mmHg and room temperature (25° C.)
Sources & evidence
- ORD record
- ord-ed12e286c15847118ff3daf764d3dcf5
- Source dataset
- uspto-grants-2014_12
- Patent number
- US08912353B2
Reaction notes
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