1,1,1,3-Tetrachloropropane → 1,1,3-Trichloropropene

HRID 1404753Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1404753
[Cl:1]Cl.[Cl:3][C:4]([Cl:9])([Cl:8])[CH2:5][CH2:6][Cl:7]>>[Cl:3][C:4]([Cl:8])=[CH:5][CH2:6][Cl:7].[Cl:3][C:4]([Cl:9])([Cl:8])[CH:5]([Cl:1])[CH2:6][Cl:7].[Cl:9][C:4]([Cl:8])=[C:5]([Cl:1])[CH2:6][Cl:7]

Komponenten

5

Edukt 2

HCID 140561,1,1,3-TetrachloropropaneHCID 24526Chlorine

Produkt 3

HCID 173781,1,3-TrichloropropeneHCID 252811,1,2,3-Tetrachloro-1-propeneHCID 134544911,1,1,2,3-Pentachloropropane

Versuchsvorschrift

Chlorine conversion was 99%; 1,1,1,3-tetrachloropropane conversion was 99%. The yields of 1,1,3-trichloropropene, 1,1,1,2,3-pentachloropropane, and 1,1,2,3-tetrachloropropene on 1,1,1,3-tetrachloropropane fed were 3.4, 82.9, and 8.1 percent, respectively. The yield of the same four undesired prominent high-boiling byproducts was 4.2 wt % in the reactor effluent.

Quellen und Nachweise

ORD-Eintrag
ord-20e7d257e82148079232eb596664a76e
Quelldatensatz
uspto-grants-2014_12
Patentnummer
US08912372B2

Notizen zur Reaktion

Wird geladen…