1-Naphthol → Benzophenone

HRID 1404824Notes

Reaction equation

HRID 1404824 reaction equation
[CH:1]1[CH:2]=[CH:3][C:4]2[C:5](=[CH:7][CH:8]=[CH:9][C:10]=2[OH:11])[CH:6]=1.CS[C:14]1[CH:19]=CC=C[C:15]=1SC>>[C:10]([C:4]1[CH:5]=[CH:6][CH:1]=[CH:2][CH:3]=1)(=[O:11])[C:9]1[CH:8]=[CH:7][CH:19]=[CH:14][CH:15]=1

Participants

3

Reactant 2

HCID 70051-NaphtholHCID 1375751,2-Bis(methylsulfanyl)benzene

Product 1

HCID 3102BenzophenoneYield 80%

Procedure

Thereafter, this naphthol compound was coupled with 1,2-dimethylthiobenzene in the same manner as in Example 17 to obtain a benzophenone derivative represented by the following formula (50) at a yield of 80%.

Sources & evidence

ORD record
ord-786c6d3a546a44e792d274c9e5e7a9a5
Source dataset
uspto-grants-2014_12
Patent number
US08916071B2

Reaction notes

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