m-Chloroperbenzoic acid → HCID 86637603, compound

Participants

Reaction Steps

To 600 mg (2.0 mmol) of trifluoromethylthioethyl p-toluenesulfonate in 10 mL of dichloromethane at 20 to 25° C. was added 493 mg (2.2 mmol of peracid) of 77% m-chloroperbenzoic acid. After stirring for about 12 hours, the mixture was washed with aqueous sodium sulfite, aqueous sodium bicarbonate, and the organic layer was dried using phase separating paper. Removal of solvent by rotoevaporation gave 630 mg (2.0 mmol, 100% yield) of trifluoromethylsulfinylethyl p-toluenesulfonate.

Provenance & Evidence