Stannous Chloride → HCID 22411260, compound

Participants

Reaction Steps

A mixture of 3,4-dinitro-N-pyridin-2-yl-benzamid (725 mg, 2.5 mmol) and SnCl2×2H2O (5.7 g, 25.2 mmol) was stirred in 20 mL ethanol under argon. After stirring for 1 h the mixture was cooled and diluted with sat. NaHCO3 (aq). The aq. phase was extracted with ethyl acetate, dried over Na2SO4 and concentrated i.vac. The residue was purified by chromatography on silica gel (eluent gradient: dichloromethane/methanol=50:1->10:1)

Provenance & Evidence