Methanol → HCID 178462740, compound

HRID 1408267Notes

Reaction equation

HRID 1408267 reaction equation
[CH:1]([N:3]1[CH:7]=[CH:6][N:5]=[CH:4]1)=[CH2:2].[CH2:8]([Br:20])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].CO>C(OCC)C>[Br-:20].[CH:1]([N+:3]1[CH:7]=[CH:6][N:5]([CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9][CH3:8])[CH:4]=1)=[CH2:2]

Participants

5

Reactant 3

HCID 887MethanolHCID 89191-BromododecaneHCID 661711-Vinylimidazole

Product 1

HCID 178462740HCID 178462740, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Conditions

Temperature
60 °C

Procedure

(From Yuan & Antonietti, DOI: 10.1021/ma102858b.) A solution/suspension comprising 0.1 mol of 1-vinylimidazole, 0.1 mol of n-dodecyl bromide and 30 mL of methanol were loaded into a 100 mL reactor. The mixture was stirred at 60° C. for 15 h. After cooling the reaction mixture was added dropwise into 1 L of diethyl ether. The white precipitate was filtered off and dried at room temperature to yield a powder.

Workup

  1. customwere loaded into a 100 mL reactor
  2. temperatureAfter cooling the reaction mixture
  3. filtrationThe white precipitate was filtered off
  4. customdried at room temperature
  5. customto yield a powder

Sources & evidence

ORD record
ord-1f36f05c996147e8a4ec03e260357161
Source dataset
uspto-grants-2014_12
Patent number
US08920682B2

Reaction notes

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