HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,3,2-Dioxathiolane, 2,2-dioxide → Cyclohexylamine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,3,2-Dioxathiolane, 2,2-dioxide | HCID 14075 | — |
| Reactant | N-Methyl-gamma-phenyl-benzenepropanamine hydrochloride (1:1) | HCID 21467371 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | Cyclohexylamine | HCID 7965 | — |
| Product | n-Hexyl sulphate lithium salt | HCID 23693704 | — |
Reaction Steps
N-methyl-3,3-diphenyl-propylamine hydrochloride, m.p. 159°-61° C. By a procedure analogous to that given above ethylene sulphate is reacted with butyllithium to give n-hexyl sulphate lithium salt which with cyclohexylamine gives N-cyclohexyl-n-hexylamine (b.p. 66° C./0.6).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04249003 |
| Source dataset | uspto-grants-1981_02 |
| ORD ID | ord-3aaa0806a3534c77a7e2bc244df9db2b |
| Source note | uspto-grants-1981_02 |