Ammonia → HCID 178494684, compound

HRID 1413249Notes

Reaction equation

HRID 1413249 reaction equation
Cl.[CH3:2][O:3][CH2:4][C:5](=[NH:9])OCC.[OH:10][CH2:11][C:12]([CH2:14]O)=O.[NH3:16]>>[CH3:2][O:3][CH2:4][C:5]1[NH:9][CH:14]=[C:12]([CH2:11][OH:10])[N:16]=1

Participants

4

Reactant 3

HCID 222AmmoniaHCID 670DihydroxyacetoneHCID 12816254Ethyl 2-methoxyethanecarboximidate hydrochloride

Product 1

HCID 178494684HCID 178494684, compound

Procedure

A 307.2 gm. portion of ethyl 2-methoxyacetimidate hydrochloride [Rule, J. Chem. Soc. 113, 9 (1918)] and 180 gm. of 1,3-dihydroxyacetone in 1 liter of liquid ammonia are reacted as described in Example 3 giving the desired product as an oil. A crystalline picrate salt (m.p. 175°-178° C.) is obtained by heating the oily product and picric acid in water.

Sources & evidence

ORD record
ord-50a29ab7ea68443ab05ea575d12c1167
Source dataset
uspto-grants-1981_02
Patent number
USRE030511

Reaction notes

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