p-Toluenesulfonyl isocyanate → HCID 53804481, compound

HRID 1413312Notes

Reaction equation

HRID 1413312 reaction equation
[CH3:1][C:2]1([CH3:15])[NH:6][CH2:5][CH:4]([CH2:7][O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[O:3]1.[C:16]1([CH3:28])[CH:21]=[CH:20][C:19]([S:22]([N:25]=[C:26]=[O:27])(=[O:24])=[O:23])=[CH:18][CH:17]=1>C1C=CC=CC=1>[CH3:1][C:2]1([CH3:15])[N:6]([C:26](=[O:27])[NH:25][S:22]([C:19]2[CH:20]=[CH:21][C:16]([CH3:28])=[CH:17][CH:18]=2)(=[O:23])=[O:24])[CH2:5][CH:4]([CH2:7][O:8][C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[O:3]1

Participants

4

Reactant 2

HCID 77703p-Toluenesulfonyl isocyanateHCID 20291473HCID 20291473, compound

Product 1

HCID 53804481HCID 53804481, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent2×

Procedure

To 20.7 milliliters of 2,2-dimethyl-5-phenoxymethyl oxazolidine, 25 percent w/v in 50 milliliters of benzene was added 419 grams of p-toluene sulfonyl isocyanate. Upon completion of the reaction the solvent, benzene, was removed in vacuo. There was obtained 12.8 grams of the title compound, as a glass. Analytical data supports the structure.

Workup

  1. customwas removed in vacuo

Sources & evidence

ORD record
ord-ca1b2f4adebf4720bfe0090d7f681d6c
Source dataset
uspto-grants-1981_02
Patent number
US04249932

Reaction notes

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