O-Allylhydroxylamine → HCID 178460156, compound

HRID 1413317Notes

Reaction equation

HRID 1413317 reaction equation
[C:1]([CH:6]1[C:11](=[O:12])[CH2:10][CH:9]([CH2:13][CH2:14][S:15][CH3:16])[CH2:8][C:7]1=[O:17])(=O)[CH2:2][CH2:3][CH3:4].[CH2:18]([O:21][NH2:22])[CH:19]=[CH2:20]>C(O)C>[CH2:18]([O:21][NH:22][C:1](=[C:6]1[C:11](=[O:12])[CH2:10][CH:9]([CH2:13][CH2:14][S:15][CH3:16])[CH2:8][C:7]1=[O:17])[CH2:2][CH2:3][CH3:4])[CH:19]=[CH2:20]

Participants

4

Reactant 2

HCID 420841O-AllylhydroxylamineHCID 20291508HCID 20291508, compound

Product 1

HCID 178460156HCID 178460156, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

2.6 g of 2- butyryl-5-(2-methylthioethyl)-cyclohexane-1,3-dione was allowed to react with 0.8 g of allyloxyamine at room temperature for 10 hours in 20 ml of ethanol. After completion of the reaction, the resulting reaction solution was treated as in Example 1 to obtain 3 g of the desired compound as colorless oily material. nD27 1.5402

Workup

  1. customAfter completion of the reaction
  2. customthe resulting reaction solution
  3. additionwas treated as in Example 1

Sources & evidence

ORD record
ord-1d353722137c4772baa4bc6dd15dbb44
Source dataset
uspto-grants-1981_02
Patent number
US04249937

Reaction notes

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