O-Allylhydroxylamine → HCID 178460157, compound

HRID 1413320Notes

Reaction equation

HRID 1413320 reaction equation
[C:1]([CH:6]1[C:11](=[O:12])[CH:10]([C:13]([O:15][CH3:16])=[O:14])[CH:9]([CH2:17][CH2:18][S:19]([CH3:22])(=[O:21])=[O:20])[CH2:8][C:7]1=[O:23])(=O)[CH2:2][CH2:3][CH3:4].[CH2:24]([O:27][NH2:28])[CH:25]=[CH2:26]>C(O)C>[CH2:24]([O:27][NH:28][C:1](=[C:6]1[C:11](=[O:12])[CH:10]([C:13]([O:15][CH3:16])=[O:14])[CH:9]([CH2:17][CH2:18][S:19]([CH3:22])(=[O:21])=[O:20])[CH2:8][C:7]1=[O:23])[CH2:2][CH2:3][CH3:4])[CH:25]=[CH2:26]

Participants

4

Reactant 2

HCID 420841O-AllylhydroxylamineHCID 20291513HCID 20291513, compound

Product 1

HCID 178460157HCID 178460157, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

3.5 g of 2-butyryl-5-(2-methylsulfonylethyl)-4-methoxycarbonyl-cyclohexane-1,3-dione was allowed to react with 0.9 g of allyloxyamine at room temperature for 5 hours in 20 ml of ethanol. After completion of the reaction, the resulting reaction solution was treated as in Example 1 to obtain 3.1 g of white crystal of the desired compound. m.p. 96.5° C.

Workup

  1. customAfter completion of the reaction
  2. customthe resulting reaction solution
  3. additionwas treated as in Example 1

Sources & evidence

ORD record
ord-0da5c45f02d34da790797c56c275cce0
Source dataset
uspto-grants-1981_02
Patent number
US04249937

Reaction notes

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