Butanal → 1,1-Dibutoxybutane

HRID 1413386Notes

Reaction equation

HRID 1413386 reaction equation
[CH:1](=[O:5])[CH2:2][CH2:3][CH3:4]>FC(F)(F)C([O-])=O.[Ru+3].FC(F)(F)C([O-])=O.FC(F)(F)C([O-])=O>[CH2:1]([O:5][CH:1]([O:5][CH2:1][CH2:2][CH2:3][CH3:4])[CH2:2][CH2:3][CH3:4])[CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 1

HCID 261Butanal

Product 1

HCID 222101,1-Dibutoxybutane

Reagents, catalysts & solvents 1

HCID 23468319HCID 23468319, compoundCatalyst

Procedure

Example 3 is repeated, while replacing ruthenium chloride with ruthenium trifluoroacetate, the other conditions of the example being unchanged. 13.8 m.moles butanal and 32 m.moles 1,1-dibutoxybutane have been formed.

Sources & evidence

ORD record
ord-a96c9cc5d05144e38c9e41138f3e6955
Source dataset
uspto-grants-1981_02
Patent number
US04250121

Reaction notes

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