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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1413420Generated: November 2, 2026

Isobutylene → 1-tert-Butyl-4-(3-chloro-2-methylpropyl)benzene

https://huagongshe.com/reaction/1413420

Reaction equation

Participants

RoleNameHCIDCharge
ReactantIsobutyleneHCID 8255—
ReactantHydrofluoric AcidHCID 14917—
Reactant(3-Chloro-2-methylpropyl)benzeneHCID 13510156—
Product1-tert-Butyl-4-(3-chloro-2-methylpropyl)benzeneHCID 13251817—
Product(3-Chloro-2-methylpropyl)benzeneHCID 13510156—

Reaction Steps

20 parts by weight of isobutene are passed into a mixture of 68 parts by weight of 2-methyl-3-phenylpropyl chloride and 3 parts by weight of hydrogen fluoride at 0° C. The mixtuure is then stirred for 12 hours at room temperature. The crude product is washed with water, dried over Na2CO3 and distilled. 36 parts by weight of 2-methyl-3-phenylpropyl chloride, boiling point 105° C./16 mm Hg and 32 parts by weight of 2-methyl-3-(p-tert.-butylphenyl)-propyl chloride, boiling point 80°-81° C./0.02 mm Hg, are obtained.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS04250123
Source datasetuspto-grants-1981_02
ORD IDord-20ecfde56c9240da94a0891ab9d4a446
Source noteuspto-grants-1981_02