HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isobutylene → 1-tert-Butyl-4-(3-chloro-2-methylpropyl)benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isobutylene | HCID 8255 | — |
| Reactant | Hydrofluoric Acid | HCID 14917 | — |
| Reactant | (3-Chloro-2-methylpropyl)benzene | HCID 13510156 | — |
| Product | 1-tert-Butyl-4-(3-chloro-2-methylpropyl)benzene | HCID 13251817 | — |
| Product | (3-Chloro-2-methylpropyl)benzene | HCID 13510156 | — |
Reaction Steps
20 parts by weight of isobutene are passed into a mixture of 68 parts by weight of 2-methyl-3-phenylpropyl chloride and 3 parts by weight of hydrogen fluoride at 0° C. The mixtuure is then stirred for 12 hours at room temperature. The crude product is washed with water, dried over Na2CO3 and distilled. 36 parts by weight of 2-methyl-3-phenylpropyl chloride, boiling point 105° C./16 mm Hg and 32 parts by weight of 2-methyl-3-(p-tert.-butylphenyl)-propyl chloride, boiling point 80°-81° C./0.02 mm Hg, are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04250123 |
| Source dataset | uspto-grants-1981_02 |
| ORD ID | ord-20ecfde56c9240da94a0891ab9d4a446 |
| Source note | uspto-grants-1981_02 |