Methyl 2-anilinobenzoate → HCID 20471363, compound

HRID 1413636Notes

Reaction equation

HRID 1413636 reaction equation
[CH2:1]([N:3]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5]([C:12]([C:14]2[CH:22]=[CH:21][CH:20]=[CH:19][C:15]=2[C:16]([OH:18])=O)=[O:13])=[C:4]1[CH3:23])[CH3:2].[NH:24]([C:31]1[CH:40]=[CH:39][CH:38]=[CH:37][C:32]=1[C:33]([O:35][CH3:36])=[O:34])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>>[CH2:1]([N:3]1[C:11]2[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=2)[C:5]([C:12]2([N:24]([C:31]3[CH:40]=[CH:39][CH:38]=[CH:37][C:32]=3[C:33]([O:35][CH3:36])=[O:34])[C:25]3[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=3)[C:14]3[C:15](=[CH:19][CH:20]=[CH:21][CH:22]=3)[C:16](=[O:18])[O:13]2)=[C:4]1[CH3:23])[CH3:2]

Participants

3

Procedure

Following a procedure similar to that described in Example 1A but employing 3.1 g of 2-(1-ethyl-2-methyl-3-indolylcarbonyl)benzoic acid and 2.3 g of methyl 2-anilinobenzoate there was obtained 0.4 g of 3-(1-ethyl-2-methyl-3-indolyl)-3-[N-(2-methoxycarbonylphenyl)-N-phenylamino]phthalide, m.p. 80°-115°. A toluene solution of the product contacted with acidic clay or phenolic resin developed a pink-colored image.

Sources & evidence

ORD record
ord-c8a72b96f2fa4ff49859fe62e85a3a74
Source dataset
uspto-grants-1981_02
Patent number
US04251092

Reaction notes

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