Acetone → HCID 20563853, compound

HRID 1413668Notes

Reaction equation

HRID 1413668 reaction equation
[Cl:1][C:2]1[C:3]([N+:16]([O-:18])=[O:17])=[C:4]([S:12](Cl)(=[O:14])=[O:13])[C:5]([CH3:11])=[CH:6][C:7]=1[N+:8]([O-:10])=[O:9].CC(C)=O.[NH3:23]>O>[Cl:1][C:2]1[C:3]([N+:16]([O-:18])=[O:17])=[C:4]([S:12]([NH2:23])(=[O:14])=[O:13])[C:5]([CH3:11])=[CH:6][C:7]=1[N+:8]([O-:10])=[O:9]

Participants

5

Reactant 3

HCID 180Acetone2×HCID 222AmmoniaHCID 20563848HCID 20563848, compound

Product 1

HCID 20563853HCID 20563853, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

4-Chloro-3,5-dinitro-o-toluenesulfonyl chloride (10 grams, 0.0318 mole) is dissolved in 150 ml. of acetone and chilled to -15° C. Ammonia (1.08 grams, 0.064 mole) is condensed and then vaporized into the acetone solution. When the addition is complete, the reaction mixture is poured into an equal volume of water and the precipitated solid collected. The crude yield of white solid is 6.8 grams with melting point 205° C. to 215° C.

Workup

  1. customcondensed
  2. additionWhen the addition
  3. customthe precipitated solid collected

Sources & evidence

ORD record
ord-5d6986873bef4712bdc739003a85aa21
Source dataset
uspto-grants-1981_02
Patent number
US04251264

Reaction notes

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