HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Tetrachlorophthalic anhydride → 2-[(1-n-Octyl-2-methyl-3-indolyl)carbonyl]-3,4,5,6-tetrachlorobenzoic acid
Beteiligte Stoffe
| Rolle | Name | HCID | Einwaage |
|---|---|---|---|
| Edukt | Tetrachlorophthalic anhydride | HCID 8326 | — |
| Edukt | 1H-Indole, 2-methyl-1-octyl- | HCID 170708 | — |
| Edukt | Aluminum(III) Chloride | HCID 6451240 | — |
| Produkt | 2-[(1-n-Octyl-2-methyl-3-indolyl)carbonyl]-3,4,5,6-tetrachlorobenzoic acid | HCID 53801848 | — |
Reaktionsschritte
Proceeding in the same manner as that described in part A of Example 6 above, 14.3 g (0.05 mole) of tetrachlorophthalic anhydride, 16.0 g (0.052 mole) of 76.5 percent active 1-n-octyl-2-methylindole and 13.3 g (0.10 mole) of aluminum chloride were interacted to obtain 2-[(1-n-octyl-2-methyl-3-indolyl)carbonyl]-3,4,5,6-tetrachlorobenzoic acid (Formula VIII: R0 =R1 =R2 =R3 =Cl; R5 =CH3 ; R6 =(CH2)7CH3 ; Y1 =H), a pale orange solid melting at 132°-134° C. The infrared spectrum, showing a maximum at 1745 cm-1 (C=O; s) and the nuclear magnetic resonance spectrum was in accord with the structure.
Herkunft & Nachweise
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patentnummer | US04251446 |
| Quelldatensatz | uspto-grants-1981_02 |
| ORD ID | ord-b5840b4ae6324796b6b618a8b5675358 |
| Quellennotiz | uspto-grants-1981_02 |