m-Chloroperbenzoic acid → Oxirane, (2,2-diphenylethyl)-

HRID 1414456Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1414456
[C:1]1([CH:7]([C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[CH2:8][CH:9]=[CH2:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.ClC1C=CC=C(C(OO)=[O:25])C=1>C(Cl)(Cl)Cl>[O:25]1[CH:9]([CH2:8][CH:7]([C:11]2[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=2)[C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH2:10]1

Komponenten

4

Edukt 2

HCID 70297m-Chloroperbenzoic acidHCID 118306504,4-Diphenyl-1-butene

Produkt 1

HCID 9991206Oxirane, (2,2-diphenylethyl)-

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 6212ChloroformLösungsmittel2×

Reaktionsbedingungen

Temperatur
25 °C

Versuchsvorschrift

A solution of 96.2 g. of 4,4-diphenyl-1-butene dissolved in 400 ml. of chloroform was added dropwise over one hour to a cold (0° C) suspension of 110.0 g. of m-chloroperbenzoic acid in 700 ml. of chloroform. The reaction mixture was warmed to about 25° C. and stirred for four hours. The reaction mixture was then washed with aqueous 2N sodium hydroxide solution, with water, and dried. Evaporation of the solvent under reduced pressure provided 158.3 g. of a yellow oil as the crude product. The oil was distilled to afford 1,2-epoxy-4,4-diphenyl-butane. B.P. 124°-126° C at 0.03 torr.

Aufarbeitung

  1. washThe reaction mixture was then washed with aqueous 2N sodium hydroxide solution, with water
  2. customdried
  3. customEvaporation of the solvent under reduced pressure
  4. customprovided 158.3 g
  5. distillationThe oil was distilled

Quellen und Nachweise

ORD-Eintrag
ord-918efaff09474482962411ae263be805
Quelldatensatz
uspto-grants-1977_01
Patentnummer
US04001328

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