HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 2-Propynyloxytetrahydropyran
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | 3,4-dihydro-2H-pyran | HCID 8080 | — |
| Reactant | Prop-1-yn-1-ol | HCID 6432594 | — |
| Product | 2-Propynyloxytetrahydropyran | HCID 21468746 | — |
Reaction Steps
Prop-1-ynol was added to dihydropyran in the presence of hydrochloric acid to give prop-1-ynyltetrahydropyranyl ether. The ether was alkylated with 5-methylhexyl bromide. The resultant product was hydrolyzed with sulfuric acid to the desired alcohol, 8-methylnon-2yn-1-ol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04001454 |
| Source dataset | uspto-grants-1977_01 |
| ORD ID | ord-f5081bb269eb4d25882a9c4632b1de13 |
| Source note | uspto-grants-1977_01 |