HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → 5-[(4-Methylphenyl)sulfanyl]-2-nitroaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | 4-Methylbenzenethiol | HCID 7811 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | 5-Chloro-2-nitroaniline | HCID 74218 | — |
| Solvent | Water | HCID 962 | — |
| Product | 5-[(4-Methylphenyl)sulfanyl]-2-nitroaniline | HCID 20362819 | — |
Reaction Steps
A mixture of 2.5 g. 2-amino-4-chloro-1-nitrobenzene, 3.6 g. p-thiocresol, 4.2 g. potassium carbonate in 20 ml. dimethylformamide is stirred overnight at room temperature, then poured into water. The crude product, recrystallized from methanol, gives 2-amino-4-(p-methylphenylthio)-1-nitrobenzene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04002640 |
| Source dataset | uspto-grants-1977_01 |
| ORD ID | ord-476f98abd7b544b7b4a2279f3a660654 |
| Source note | uspto-grants-1977_01 |