2,3-Dihydro-1-benzofuran-6-ol → 6-[(6-Methyloct-5-en-2-yl)oxy]-2,3-dihydro-1-benzofuran

HRID 1414826Notes

Reaction equation

HRID 1414826 reaction equation
C1(C)C=CC(S(O[CH:11]([CH3:19])[CH2:12][CH2:13][CH:14]=[C:15]([CH3:18])[CH2:16][CH3:17])(=O)=O)=CC=1.[OH:21][C:22]1[CH:30]=[CH:29][C:25]2[CH2:26][CH2:27][O:28][C:24]=2[CH:23]=1>>[CH3:19][CH:11]([O:21][C:22]1[CH:30]=[CH:29][C:25]2[CH2:26][CH2:27][O:28][C:24]=2[CH:23]=1)[CH2:12][CH2:13][CH:14]=[C:15]([CH3:18])[CH2:16][CH3:17]

Participants

3

Reactant 2

HCID 122365402,3-Dihydro-1-benzofuran-6-olHCID 542251391,5-Dimethyl-4-heptenyl p-toluenesulfonate

Product 1

HCID 544631146-[(6-Methyloct-5-en-2-yl)oxy]-2,3-dihydro-1-benzofuran

Procedure

1,5-dimethyl-4-heptenyl p-toluenesulfonate and 6-hydroxy-2,3-dihydrobenzofuran are reacted to produce 6-[(1,5-dimethyl-4-heptenyl)-oxy]-2,3-dihydrobenzofuran of boiling point (bulb-tube) 120° C./0.02 mmHg; nD20 = 1.5226; and

Sources & evidence

ORD record
ord-c3d104033ffc4c6d8eb0e9de3b86cd48
Source dataset
uspto-grants-1977_01
Patent number
US04002647

Reaction notes

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