2,3-Dihydro-1-benzofuran-6-ol → 6-[(6-Ethoxy-6-methylheptan-2-yl)oxy]-2,3-dihydro-1-benzofuran

HRID 1414827Notes

Reaction equation

HRID 1414827 reaction equation
C1(C)C=CC(S(O[CH:11]([CH3:21])[CH2:12][CH2:13][CH2:14][C:15]([O:18][CH2:19][CH3:20])([CH3:17])[CH3:16])(=O)=O)=CC=1.[OH:23][C:24]1[CH:32]=[CH:31][C:27]2[CH2:28][CH2:29][O:30][C:26]=2[CH:25]=1>>[CH2:19]([O:18][C:15]([CH3:16])([CH3:17])[CH2:14][CH2:13][CH2:12][CH:11]([O:23][C:24]1[CH:32]=[CH:31][C:27]2[CH2:28][CH2:29][O:30][C:26]=2[CH:25]=1)[CH3:21])[CH3:20]

Participants

3

Reactant 2

HCID 122365402,3-Dihydro-1-benzofuran-6-olHCID 53725996HCID 53725996, compound

Product 1

HCID 214851356-[(6-Ethoxy-6-methylheptan-2-yl)oxy]-2,3-dihydro-1-benzofuran

Procedure

5-ethoxy-1,5-dimethylhexyl p-toluenesulfonate and 6-hydroxy-2,3-dihydrobenzofuran are reacted to produce 6-[(5-ethoxy-1,5-dimethylhexyl)-oxy]-2,3-dihydrobenzofuran of boiling point (bulb-tube) 127° C./0.02 mmHg; nD24 = 1.5023.

Sources & evidence

ORD record
ord-e944dab552594c9fb9771d7dca11fd0b
Source dataset
uspto-grants-1977_01
Patent number
US04002647

Reaction notes

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