HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → HCID 54574644, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Norbornadiene | HCID 8473 | — |
| Reactant | HCID 178455850 | HCID 178455850 | — |
| Product | HCID 54574644 | HCID 54574644 | 73% |
Reaction Steps
The procedure of Example I was repeated on a larger scale by reacting 195 mmoles of allylmagnesium bromide in diethyl ether with 218 mmoles of bicyclo[2.2.1]hepta-2,5-diene at 125° C. for 3 hours. After the oxidation and hydrolysis, distillation gave tricyclo[4.2.1.02.5 ]non-7-en-3-yl-methanol (b.p. 97°-99° C. at 1 mm Hg) in 73 percent yield based on the allylmagnesium bromide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04002691 |
| Source dataset | uspto-grants-1977_01 |
| ORD ID | ord-ee87587f7e3e405e8575e72d6ae99334 |
| Source note | uspto-grants-1977_01 |