HuagongsheHuagongshe Chemistry Print Report · For research reference only
13beta-Ethyl-3-methoxygona-1,3,5(10),8,14-pentaen-17-one → Einecs 227-699-7
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 13beta-Ethyl-3-methoxygona-1,3,5(10),8,14-pentaen-17-one | HCID 10979300 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | Einecs 227-699-7 | HCID 111113 | 59.6% |
Reaction Steps
Dissolve 13β-ethyl-3-methoxygona-1,3,5(10),8,14-pentaen-17-one (2 g) in dioxan (50 cc) containing Raney nickel (ca. 0.5 g) of moderate activity and shake with hydrogen until 160 cc., the amount corresponding to one molecular proportion has been absorbed. Recrystallize the isolated product from methanol to obtain the title product (1.2 g), m.p. 110°-125°; ultraviolet absorption peak at 280 mμ (ε13,200).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04002746 |
| Source dataset | uspto-grants-1977_01 |
| ORD ID | ord-f8615076edb24375a4f9e5b6ba5ce96a |
| Source note | uspto-grants-1977_01 |