HuagongsheHuagongshe Chemistry Print Report · For research reference only
Chloral Hydrate → HCID 68143795, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Chloral Hydrate | HCID 2707 | — |
| Reactant | Gon-4-en-3-one, 13-ethyl-17-hydroxy-, (17beta)-(+-)- | HCID 10039774 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 68143795 | HCID 68143795 | — |
Reaction Steps
Add 2.9 g. of dl-13-ethyl-17β-hydroxygon-4-en-3-one to a solution of 1.9 g. of chloral hydrate in 10 ml. of benzene at 5°C. Keep the mixture overnight at this temperature. Filter off the product and recrystallize it successively from ethyl acetate and petroleum ether-benzene to obtain the title substance, m.p. 175°-176°; ultraviolet peak at 240 mμ (ε17,500); infrared peaks at 3.10, 6.05, 6.20 μ.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04002746 |
| Source dataset | uspto-grants-1977_01 |
| ORD ID | ord-a1baf57b7bb14360968cd7c3042b4ab9 |
| Source note | uspto-grants-1977_01 |