Benzene → Silver behenate

HRID 1415094Notes

Reaction equation

HRID 1415094 reaction equation
C1C=CC=CC=1.[C:7]([OH:30])(=[O:29])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28].[Ag:31]>O>[C:7]([O-:30])(=[O:29])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28].[Ag+:31]

Participants

5

Reactant 3

HCID 241BenzeneHCID 8215Docosanoic AcidHCID 23954Silver

Product 1

HCID 164971Silver behenate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Into 100 ml benzene at 60° C, 3.4 g of behenic acid was dissolved and further 100 ml of water was added to the solution at 60° C with stirring to produce an emulsion. To the emulsion, 100 ml of an aqueous solution silver ammine complex salt at 10° C was added to form fine particles of silver behenate. The aqueous silver ammine complex salt solution was prepared by adding an aqueous ammonia solution to about 80 ml of an aqueous solution containing 1.7 g of silver nitrate and then adding water to make the total volume 100 ml.

Workup

  1. customto produce an emulsion
  2. customat 10° C
  3. additionwas added

Sources & evidence

ORD record
ord-a60c1fe7d039419081f700b2ad8d742c
Source dataset
uspto-grants-1977_01
Patent number
US04003749

Reaction notes

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